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Beilstein J. Org. Chem. 2013, 9, 1202–1209, doi:10.3762/bjoc.9.136
Graphical Abstract
Figure 1: Representative examples of carbazoles with hole-transport, host or luminescent properties.
Scheme 1: Synthetic access to N-arylated carbazoles.
Scheme 2: Proposed mechanistic motivation towards the formation of 3a.
Figure 2: FID chromatogram of the reaction mixture. Only the most intense peaks were structurally assigned. x...
Figure 3: Substrate scope. All reactions were performed using iodonium salt 1 (0.35 mmol), 1.2 equiv of prima...
Scheme 3: Synthesis of dibenzo[b,d]bromolium trifluoromethanesulfonate (6).
Scheme 4: Dibenzo[b,d]bromolium trifluoromethanesulfonate (6) and p-fluoroaniline (2f) to construct carbazole ...